NestJS is an excellent framework (they both are). I would say the fact that you're working with Angular makes NestJS a great match, unless you're splitting front and back end between developers. But even in that case I would still go with NestJS for a new project.

Regarding the single threading point, take a look at PM2 which helps to run Node in multiple processes (we use it with NestJS) https://pm2.keymetrics.io/docs/usage/cluster-mode/

Also regarding web server performance in general this is an interesting post showing how Node with outperform Java in a web situation (be careful though, best to check a few posts to make sure these aren't totally biased benchmarks!): https://www.tandemseven.com/blog/performance-java-vs-node/

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